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Puzzle 2447 ?

Puzzle 2447
http://en.lichess.org/training/2447
I can not see the reasoning/logic or why 1... Qa4 is the best move and after I made this move 1..Qa4 Black is not capturing my Queen with Qa5xQa4 but instead chooses for Ne4xBg5? Then Black allows me to do Qa4xQa5 and puzzle is solved.
I know I am beginner and try to learn chess by playing the puzzles and trying to see the reasoning/logic of the moves involved with small hopes of understanding and improving upon it.

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